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Electrochemistry for Heritage Group

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Webreports

  • / Case study 1
      Resut and discussions:
    • / Summary of the analytical study
    • / Sample 1: red pigment
    • / Sample 2: ochre pigment
    • / Sample 3: green pigment
    • / Sample 4: blue pigment
  • / Case study 2
  • / Case study 3

/ Case study 1

Analytical characterization of the roman wall paintings of the archaeological site of Cástulo (Spain)

Results and discussion / Sample 4: blue pigment

  • / Light microscopy
  • / Scanning electron microscopy-x-ray microanalysis
  • / FTIR spectroscopy
  • / Square Wave Voltammetry
  • / Atomic Force Microscopy-Voltammetry of micro/nanoparticles
  • / Scaning electrochemical microscopy

/ Square Wave Voltammetry

  • Square wave voltammograms for two earth pigments extracted from Castulo samples attached to graphite bar in contact with 0.10 M HCl aqueous solution. Potential step initiated at +0.85 V vs. Ag/AgCl (3 M NaCl) in the negative direction; potential step
    XEnlarged Square wave voltammograms for two earth pigments extracted from Castulo samples attached to graphite bar in contact with 0.10 M HCl aqueous solution. Potential step initiated at +0.85 V vs. Ag/AgCl (3 M NaCl) in the negative direction; potential step

    Square wave voltammograms for two earth pigments extracted from Castulo samples attached to graphite bar in contact with 0.10 M HCl aqueous solution. Potential step initiated at +0.85 V vs. Ag/AgCl (3 M NaCl) in the negative direction; potential step

Square wave voltammograms for two earth pigments extracted from Castulo samples attached to graphite bar in contact with 0.10 M HCl aqueous solution. Potential step initiated at +0.85 V vs. Ag/AgCl (3 M NaCl) in the negative direction; potential step increment 4 mV; square wave amplitude 25 mV; frequency 5 Hz.

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